Dechlorination Dose Calculator
Chlorinated effluent must be dechlorinated before discharge. Enter your chlorine residual and flow to size the bisulfite or sulfur dioxide feed.
Dechlorination Dose
| Item | Value |
|---|
How the calculation works
Formulas
Theoretical ratio = molecular weight of chemical ÷ molecular weight of Cl2 (70.90)
NaHSO3: 104.06 ÷ 70.90 = 1.47 mg/mg Cl2
Na2S2O5: 190.11 ÷ (2 × 70.90) = 1.34 mg/mg Cl2
SO2: 64.06 ÷ 70.90 = 0.90 mg/mg Cl2
Design dose (mg/L) = residual (mg/L) × theoretical ratio × safety factor
Feed rate (lb/day) = 8.34 × flow (MGD) × dose (mg/L)
Theoretical ratio = molecular weight of chemical ÷ molecular weight of Cl2 (70.90)
NaHSO3: 104.06 ÷ 70.90 = 1.47 mg/mg Cl2
Na2S2O5: 190.11 ÷ (2 × 70.90) = 1.34 mg/mg Cl2
SO2: 64.06 ÷ 70.90 = 0.90 mg/mg Cl2
Design dose (mg/L) = residual (mg/L) × theoretical ratio × safety factor
Feed rate (lb/day) = 8.34 × flow (MGD) × dose (mg/L)
| Chemical | Theoretical mg/mg Cl2 | Typical design ratio |
|---|---|---|
| Sodium bisulfite (NaHSO3) | 1.47 | 1.5–2.0 |
| Sodium metabisulfite (Na2S2O5) | 1.34 | 1.5 |
| Sulfur dioxide (SO2) | 0.90 | 1.0–1.2 |
Notes & limitations
Theoretical ratios come from balanced redox stoichiometry (Metcalf & Eddy, Wastewater Engineering; WEF MOP 8). Actual demand varies with mixing, contact time, and side reactions — verify the effluent total residual chlorine (TRC) with DPD testing and trim the feed.
- Size the feed system for the peak residual and peak flow combination, not the average — permit compliance is measured at all times.
- Sulfur dioxide is a toxic gas; gas feed systems need leak detection, scrubbers, and operator training per OSHA requirements.
- Liquid bisulfite products (typically ~38% solution) need a density-based conversion from the dry lb/day shown here — check the product data sheet.
- Overfeeding bisulfite depresses dissolved oxygen in the effluent; some permits limit the effluent sulfite residual as well.
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